Catalytic systems based on nickel(ii) complexes with bis(3,5-dimethylpyrazol-1-yl)methane – impact of PPh3 on the formation of precatalysts and selective dimerization of ethylene

Author:

Zubkevich S. V.1234ORCID,Tuskaev V. A.12345,Gagieva S. Ch.1234,Pavlov A. A.5674ORCID,Khrustalev V. N.8941011ORCID,Polyakova O. V.1234,Zarubin D. N.5674,Kurmaev D. A.1234,Kolosov N. A.1234,Bulychev B. M.1234

Affiliation:

1. Department of Chemistry

2. Lomonosov Moscow State University

3. Moscow 119991

4. Russian Federation

5. A. N. Nesmeyanov Institute of Organoelement Compounds

6. Russian Academy of Sciences

7. Moscow 119334

8. National Research Center “Kurchatov Institute”

9. Moscow 123182

10. Peoples’ Friendship University of Russia (RUDN University)

11. Moscow 117198

Abstract

Triphenylphosphine facilities ionization of Ni(ii) complexes with bis(3,5-dimethylpyrazol-1-yl)metane, which results in highly active catalytic systems for ethylene dimerization.

Funder

Russian Foundation for Basic Research

Council on grants of the President of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference83 articles.

1. Pyrazole and (pyrazol-1-yl)metal complexes as carbon–carbon coupling catalysts

2. S. Trofimenko , Progress in Inorganic Chemistry , 2007 , vol. 34, pp. 115–210

3. C. Pettinari , R.Pettinari and F.Marchetti , Advances in Organometallic Chemistry , Elsevier Inc. , 1st edn, 2016 , vol. 65, pp. 175–260

4. Metal complexes with heteroscorpionate ligands based on the bis(pyrazol-1-yl)methane moiety: Catalytic chemistry

5. Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands

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