Photo-chemically induced polycondensation of a pure phenolic resin for additive manufacturing

Author:

Wolff Raffael1ORCID,Ehrmann Katharina1ORCID,Knaack Patrick1ORCID,Seidler Konstanze2ORCID,Gorsche Christian2ORCID,Koch Thomas3,Stampfl Jürgen3ORCID,Liska Robert1ORCID

Affiliation:

1. Institute of Applied Synthetic Chemistry, Technische Universität Wien, Getreidemarkt 9/163 MC, 1060 Vienna, Austria

2. Cubicure GmbH, Gutheil-Schodergasse 17, Tech Park Vienna, 1230 Vienna, Austria

3. Institute of Materials Science and Technology, Technische Universität Wien, Getreidemarkt 9/308, 1060 Vienna, Austria

Abstract

Additive manufacturing of phenolic resins as a proof-of-concept for the first photo-chemical induced polycondensation by Hot Lithography. Through the dual use of a photoacidgenerator, the first pure 3D printing of Bakelite© is investigated.

Funder

Österreichische Forschungsförderungsgesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference39 articles.

1. A.Knop and W.Scheib , Chemistry and Application of Phenolic Resins , Springer-Verlag , Berlin , 1979

2. American Chemical Society National Historic Chemical Landmarks, “Bakelite: First Synthetic Plastic”, can be found under https://www.acs.org/content/acs/en/education/whatischemistry/landmarks/bakelite.html , 1993

3. L.Pilato , Phenolic Resins: A Century of Progress , Springer-Verlag , 2010

4. W.Hesse and J.Lang , in Ullmann's Encycl. Ind. Chem , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2011

5. Some aspects of curing novolac with hexamethylenetetramine

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