Isotope-selective chemistry in the Be+(2S1/2) + HOD → BeOD+/BeOH+ + H/D reaction

Author:

Chen Gary K.1234,Xie Changjian5674,Yang Tiangang1234ORCID,Li Anyang89101112ORCID,Suits Arthur G.1314154ORCID,Hudson Eric R.1234,Campbell Wesley C.1234,Guo Hua5674ORCID

Affiliation:

1. Department of Physics and Astronomy

2. University of California Los Angeles

3. Los Angeles

4. USA

5. Department of Chemistry and Chemical Biology

6. University of New Mexico

7. Albuquerque

8. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry

9. Ministry of Education

10. College of Chemistry and Materials Science

11. Northwest University

12. 710127 Xi’an

13. Department of Chemistry

14. University of Missouri

15. Columbia

Abstract

Low temperature reactions between laser-cooled Be+(2S1/2) ions and partially deuterated water (HOD) molecules have been investigated using an ion trap and interpreted with zero-point corrected quasi-classical trajectory calculations on a highly accurate global potential energy surface for the ground electronic state.

Funder

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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