Reactivity of 4Fe+(CO)n=0–2 + O2: oxidation of CO by O2 at an isolated metal atom-Reference-Cited by-同舟云学术

Reactivity of 4Fe+(CO)n=0–2 + O2: oxidation of CO by O2 at an isolated metal atom

Published:2017 Issue:13 Volume:19 Page:8768-8777
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ard Shaun G.¹²³⁴,Martinez Oscar¹²³⁴,Brown Steven A.¹²³⁴,Sawyer Jordan C.¹²³⁴,Armentrout P. B.⁵⁶⁷⁴^ORCID,Viggiano Albert A.¹²³⁴,Shuman Nicholas S.¹²³⁴^ORCID

Affiliation:

1. Air Force Research Laboratory

2. Space Vehicles Directorate

3. Kirtland Air Force Base

4. USA

5. Department of Chemistry

6. University of Utah

7. Salt Lake City

Abstract

The kinetics of Fe⁺(CO)_n + O₂ yield insight on the mechanism of O₂ bond cleavage and CO oxidation occurring at a single non-noble metal atom.

Funder

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP08703E

Reference71 articles.

1. CO Oxidation on Pt(111): AnAb InitioDensity Functional Theory Study

2. Complex pathways in dissociative adsorption of oxygen on platinum

3. Catalytic Role of Gold in Gold-Based Catalysts: A Density Functional Theory Study on the CO Oxidation on Gold

4. Anomalous Behavior of Ru for Catalytic Oxidation: A Theoretical Study of the Catalytic ReactionCO+12O2→CO2

5. In situ analysis of catalytically active Pd surfaces for CO oxidation with near ambient pressure XPS

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