Metal-free synthesis of fulleropyrrolidin-2-ols: a novel reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes

Author:

Huang Gang12345,Zhang Meng12345,Wang Hui-Juan678910,Li Fa-Bao12345ORCID,Yang Fei12345,Liu Li12345ORCID,Liu Chao-Yang678910,Asiri Abdullah M.1112131415ORCID,Alamry Khalid A.1112131415

Affiliation:

1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials

2. Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules

3. Key Laboratory of Green Preparation and Application for Functional Materials

4. Ministry of Education

5. and School of Chemistry and Chemical Engineering

6. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics

7. Wuhan Center for Magnetic Resonance

8. Wuhan Institute of Physics and Mathematics

9. Chinese Academy of Sciences

10. Wuhan 430071

11. Department of Chemistry

12. Faculty of Science

13. King Abdulaziz University

14. Jeddah 21589

15. Saudi Arabia

Abstract

The reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes in the absence of metal salts afforded a series of novel fulleropyrrolidin-2-ols in moderate yields.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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