Programming heterometallic 4f–4f′ helicates under thermodynamic control: the circle is complete-Reference-Cited by-同舟云学术

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Programming heterometallic 4f–4f′ helicates under thermodynamic control: the circle is complete

Published:2024 Issue:13 Volume:53 Page:6050-6062
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Egger Charlotte¹,Guénée Laure²,Deorukhkar Neel¹,Piguet Claude¹^ORCID

Affiliation:

1. Department of Inorganic and Analytical Chemistry, University of Geneva, 30 quai E. Ansermet, CH-1211 Geneva 4, Switzerland

2. Laboratory of Crystallography, University of Geneva, 24 quai E. Ansermet, CH-1211 Geneva 4, Switzerland

Abstract

The use of pair interactions and specific site affinities provides 63% of the heterotrimetallic HHH-[(L43Zn)LaEu]8+ helicate in solution where statistics predicts only 25% of this isomer under thermodynamic control for a stoichiometric ratio of 1 : 1 : 1.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00610K

Reference84 articles.

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4. M. G.Brik and C.-G.Ma , Theoretical Spectroscopy of Transition Metal and Rare Earth Ions , Jenny Stanford Publishing , Singapore , 2020 , ch. 6, pp. 145–244

5. R.Saez and P.Caro , Rare Earths , Editorial Complutense S.A ., Madrid , 1998

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