Black TiO2 nanoparticles with efficient photocatalytic activity under visible light at low temperature: regioselective C–N bond cleavage toward the synthesis of thioureas, sulfonamides, and propargylamines

Abstract

Several different colored forms of TiO₂ were prepared through the easy treatment of white TiO₂ and NaBH₄ as a safe hydrogen source. Then, tertiary amines were harnessed toward the regioselective synthesis of three prominent scaffolds.