Kinetics of contracting geometry-type reactions in the solid state: implications from the thermally induced transformation processes of α-oxalic acid dihydrate

Author:

Kodani Satoki12345,Koga Nobuyoshi12345ORCID

Affiliation:

1. Department of Science Education

2. Graduate School of Education

3. Hiroshima University

4. Higashi-Hiroshima 739-8524

5. Japan

Abstract

Thermally induced transformation processes of α-oxalic acid dihydrate reveal the current status of kinetic understanding.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference90 articles.

1. A. K. Galwey and M. E.Brown , Thermal Decomposition of Ionic Solids , Elsevier , Amsterdam , 1999

2. Structure and order in thermal dehydrations of crystalline solids

3. A physico-geometric approach to the kinetics of solid-state reactions as exemplified by the thermal dehydration and decomposition of inorganic solids

4. N. Koga , in Handbook of Thermal Analysis and Calorimetry , ed. S. Vyazovkin , N. Koga and C. Schick , Elsevier , Amsterdam , 2nd edn, 2018 , ch. 6, vol. 6, pp. 213–251

5. Influence of the particle size distribution on the CRTA curves for the solid-state reactions of interface shrinkage type

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