On the energetics of binding and hydride exchange in the RuH<sub>2</sub>(H<sub>2</sub>)<sub>2</sub>[P(C<sub>5</sub>H<sub>9</sub>)<sub>3</sub>)]<sub>2</sub> complex as revealed by inelastic neutron scattering and DFT studies-Reference-Cited by-同舟云学术

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On the energetics of binding and hydride exchange in the RuH₂(H₂)₂[P(C₅H₉)₃)]₂ complex as revealed by inelastic neutron scattering and DFT studies

Published:2022 Issue:30 Volume:46 Page:14649-14659
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Albinati A.¹²^ORCID,Grellier M.³⁴,Ollivier J.⁵,Georgiev P. A.⁶^ORCID

Affiliation:

1. CNR – ICCOM, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy

2. University of Milan, Milan, Italy

3. CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse, France

4. Université de Toulouse, UPS, INPT 31077 Toulouse, France

5. Institute Laue-Langevin, 6 rue Jules Horovitz, BP156, F-38042 Grenoble Cedex 9, Grenoble, France

6. Department of Condensed Matter Physics and Microelectronics, The University of Sofia, J. Bourchier, 5, Sofia 1164, Bulgaria

Abstract

Low temperature quantum rotation of dihydrogen in RuH2(H2)2[P(C5H9)3)]2 switched to a facile hydride exchange above 150 K.

Funder

Bulgarian National Science Fund

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02100E

Reference57 articles.

1. Die Basenreaktionen der Hexacarbonyle der Chromgruppe. II. �ber die Basenreaktion des Molybd�nhexacarbonyls

2. R.Bau , Transition Metal Hydrides , ACS Advances in Chemistry Series, no. 167, American Chemical Society , 1978

3. M.Peruzzini and R.Poli , Recent Advances in Hydride Chemistry , Elsevier , 2001

4. Introduction: Metal Hydrides

5. Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes

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