Probing the methanol-assisted autocatalytic formation of methanol over Cu/ZnO/Al<sub>2</sub>O<sub>3</sub> by high-pressure methanol and methyl formate pulses-Reference-Cited by-同舟云学术

Probing the methanol-assisted autocatalytic formation of methanol over Cu/ZnO/Al₂O₃ by high-pressure methanol and methyl formate pulses

Published:2022 Issue:10 Volume:7 Page:2224-2230
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Schwiderowski Philipp¹,Stürmer Sascha¹,Muhler Martin¹²^ORCID

Affiliation:

1. Laboratory of Industrial Chemistry, Ruhr-University Bochum, 44780 Bochum, Germany

2. Max Planck Institute for Chemical Energy Conversion (MPI CEC), 45470 Mülheim an der Ruhr, Germany

Abstract

Using high-pressure methanol and methyl formate pulses as a surface-sensitive operando method for high-pressure methanol synthesis over Cu/ZnO/Al2O3, the recently found autocatalytic pathway was confirmed.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RE/D2RE00185C

Reference40 articles.

1. Beyond Oil and Gas: The Methanol Economy

2. A Kinetic Model of Methanol Synthesis

3. The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts

4. Bridging the Time Gap: A Copper/Zinc Oxide/Aluminum Oxide Catalyst for Methanol Synthesis Studied under Industrially Relevant Conditions and Time Scales

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1. The Enigma of Methanol Synthesis by Cu/ZnO/Al₂O₃-Based Catalysts;Chemical Reviews;2024-04-02

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