Efficient dimerization of perfluoroolefin with strong nucleophilic ionic liquid catalysts by adjusting the interaction of anions and cations

Author:

Huang Shiqi12,Meng Xianglei234ORCID,Gao Yanzhao12,Liu Minmin25,Zhang Junjie25,Zhou Yu1ORCID,Song Yuting234,Diao Yanyan234ORCID

Affiliation:

1. College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

2. Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China

3. College of Chemical and Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

4. Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China

5. College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Abstract

Ionic liquids, as an efficient nucleophilic catalyst, is used for the first time in the dimerization of perfluoroolefin, and further promotes the greening of fluorochemical reactions.

Funder

National Natural Science Foundation of China

National Youth Foundation of China

Innovation Academy for Green Manufacture, Chinese Academy of Sciences

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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