Effect of the extended π-surface and <i>N</i>-butyl substituents of imidazoles on their reactivity, electrochemical behaviours and biological interactions of corresponding Pt(<scp>ii</scp>)-CNC carbene complexes: exploring DFT and docking interactions-Reference-Cited by-同舟云学术

Effect of the extended π-surface and N-butyl substituents of imidazoles on their reactivity, electrochemical behaviours and biological interactions of corresponding Pt(ii)-CNC carbene complexes: exploring DFT and docking interactions

Published:2024 Issue:31 Volume:48 Page:14071-14087
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Bellam Rajesh¹²^ORCID,Onunga Daniel O.³,Jaganyi Deogratius⁴⁵,Robinson Ross¹^ORCID,Mambanda Allen¹

Affiliation:

1. School of Chemistry and Physics, University of KwaZulu-Natal, Private Bag X01, Scottsville, Pietermaritzburg 3209, South Africa

2. Department of Chemistry, Medi-Caps University, A. B. Road, Pigdamber, Rau, Indore 453331, Madhya Pradesh, India

3. Department of Chemistry, Maseno University, P.O. Box 333-40105, Maseno, Kenya

4. School of Pure and Applied Sciences, Mount Kenya University, P.O. Box 342-01000, Thika, Kenya

5. Department of Chemistry, Durban University of Technology, P.O. Box 1334, Durban 4000, South Africa

Abstract

The extended π surface and the N-butyl arms on the bis(3-methylimidazolium-1-yl)pyridine ligand cause prominent σ-inductive effect and steric influences on the complexes which stabilises the metal centres which leads to damping in their reactivity.

Funder

Inyuvesi Yakwazulu-Natali

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ00552J

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