New Ni4Na2-phenylgermsesquioxane architecture: synthesis, structure and slow dynamic behaviour

Author:

Kulakova Alena N.12345,Bilyachenko Alexey N.12345ORCID,Korlyukov Alexander A.12367,Long Jérôme89101112ORCID,Levitsky Mikhail M.123,Shubina Elena S.123,Guari Yannick89101112ORCID,Larionova Joulia89101112ORCID

Affiliation:

1. A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences

2. 119991 Moscow

3. Russia

4. Peoples’ Friendship University of Russia (RUDN University)

5. 117198 Moscow

6. Pirogov Russian National Research Medical University

7. 117997 Moscow

8. Institut Charles Gerhardt

9. UMR5253

10. University of Montpellier

11. ENSCM

12. CNRS

Abstract

The first Ni(ii)-based germaniumsesquioxane cage compound [(PhGeO1.5)10(NiO)4(NaO0.5)2] presents a unique sandwich-like structure and exhibits slow dynamics of the magnetization.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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