Electrocatalytic hydrogenation of pyridinium enabled by surface proton transfer reactions
Author:
Affiliation:
1. Department of Chemical and Biological Engineering
2. Princeton University
3. Princeton
4. USA
5. Department of Chemistry
Abstract
It is observed for the first time that pyridinium is hydrogenated at Pt electrodes in electrochemical conditions consistent with those previously shown to yield selective reduction of carbon dioxide to methanol and formic acid.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C6CY02487D
Reference51 articles.
1. Selective Solar-Driven Reduction of CO2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell
2. Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights
3. Electrochemistry of Acids on Platinum. Application to the Reduction of Carbon Dioxide in the Presence of Pyridinium Ion in Water
4. Functional Role of Pyridinium during Aqueous Electrochemical Reduction of CO2 on Pt(111)
5. Theoretical Insights into Pyridinium-Based Photoelectrocatalytic Reduction of CO2
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