Direct observation of breaking of the intramolecular H-bond, and slowing down of the proton motion and tuning its mechanism in an HBO derivative-Reference-Cited by-同舟云学术

Direct observation of breaking of the intramolecular H-bond, and slowing down of the proton motion and tuning its mechanism in an HBO derivative

Published:2015 Issue:22 Volume:17 Page:14569-14581
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Alarcos Noemí¹²³⁴⁵,Gutiérrez Mario¹²³⁴⁵,Liras Marta⁶⁷⁸⁹,Sánchez Félix⁶⁷⁸⁹,Moreno Miquel¹⁰¹¹¹²⁹,Douhal Abderrazzak¹²³⁴⁵

Affiliation:

1. Departamento de Química Física

2. Facultad de Ciencias Ambientales y Bioquímica

3. and INAMOL

4. Universidad de Castilla-La Mancha

5. 45071 Toledo

6. Instituto de Química Orgánica General

7. IQOG-CSIC

8. 28006 Madrid

9. Spain

10. Departament de Química

11. Universitat Autónoma de Barcelona

12. 08193 Barcelona

Abstract

Exploring the mechanism of proton motion coupled to a charge-transfer reaction in a new HBO derivative in solution using steady-state and ultrafast emission spectroscopy shows an abnormal spectroscopic and dynamical behavior.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01437A

Reference45 articles.

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3. Femtosecond molecular dynamics of tautomerization in model base pairs

4. Proton-transfer reaction dynamics

5. Ultrafast Hydrogen Bonding Dynamics and Proton Transfer Processes in the Condensed Phase, ed. T. Elsaesser and H. J. E. Bakker, Kluwer Academic Publisher, 2002

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