Atomically-dispersed NiN4–Cl active sites with axial Ni–Cl coordination for accelerating electrocatalytic hydrogen evolution-Reference-Cited by-同舟云学术

Atomically-dispersed NiN4–Cl active sites with axial Ni–Cl coordination for accelerating electrocatalytic hydrogen evolution

Published:2022 Issue: Volume: Page:
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Li Min¹,Wang Minmin¹,Liu Dongyuan²,Pan Yuan¹^ORCID,Liu Shoujie³^ORCID,Sun Kaian¹,Chen Yanju¹,Zhu Houyu²^ORCID,Guo Wenyue²^ORCID,Li Yanpeng¹,Cui Zhiming⁴^ORCID,Liu Bin¹,Liu Yunqi¹,Liu Chenguang¹

Affiliation:

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, China

2. School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China

3. College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, China

4. Key Laboratory of Fuel Cell Technology of Guangdong Province, South China University of Technology, Guangzhou, 510641, China

Abstract

The NiN4–Cl SAs/N–C electrocatalyst consisting of NiN4–Cl active sites with axial Ni–Cl coordination was synthesized. The axial Cl-coordination modulates the electronic configuration of Ni–N4 sites and enhances the interaction of Ni–H efficiently.

Funder

National Natural Science Foundation of China

PetroChina Innovation Foundation

Taishan Scholar Project of Shandong Province

Natural Science Foundation of Shandong Province

China University of Petroleum, Beijing

Fundamental Research Funds for the Central Universities

Guangdong Key Laboratory of Fuel Cell Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry