An <i>in situ</i> generated proton initiated aromatic fluoroalkylation <i>via</i> electron donor–acceptor complex photoactivation-Reference-Cited by-同舟云学术

An in situ generated proton initiated aromatic fluoroalkylation via electron donor–acceptor complex photoactivation

Published:2024 Issue:12 Volume:26 Page:7198-7205
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Huang Panyi¹,Lv Chun¹,Song Haijing¹,Wang Chenjing¹,Du Junze¹,Li Jianjun¹²^ORCID,Sun Bin¹²,Jin Can¹²^ORCID

Affiliation:

1. College of Pharmaceutical Sciences, Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou 310014, China

2. Key Laboratory for Green Pharmaceutical Technologies and Related Equipment of Ministry of Education and Key Laboratory of Pharmaceutical Engineering of Zhejiang Province, Zhejiang University of Technology, Hangzhou 310014, PR China

Abstract

In situ-generated protonated aromatic hydrocarbons overcome their intrinsic electronic properties to serve as catalytic electron acceptors, avoiding the use of photocatalysts, metals, and redox reagents to achieve fluoroalkylation.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Zhejiang University of Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D4GC00728J

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