Effects of repeat unit charge density on the physical and electrochemical properties of novel heterocationic poly(ionic liquid)s-Reference-Cited by-同舟云学术

Effects of repeat unit charge density on the physical and electrochemical properties of novel heterocationic poly(ionic liquid)s

Published:2021 Issue:1 Volume:45 Page:53-65
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Cotessat Merlin¹²³,Flachard Dimitri⁴⁵⁶⁷⁸,Nosov Daniil¹²³^ORCID,Lozinskaya Elena I.⁹¹⁰¹¹^ORCID,Ponkratov Denis O.⁹¹⁰¹¹,Schmidt Daniel F.¹²³,Drockenmuller Eric¹²³^ORCID,Shaplov Alexander S.¹²³^ORCID

Affiliation:

1. Luxembourg Institute of Science and Technology (LIST)

2. L-4362 Esch-sur-Alzette

3. Luxembourg

4. Univ. Lyon

5. Université Lyon 1

6. CNRS

7. Ingénierie des Matériaux Polymères

8. UMR 5223

9. A. N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences (INEOS RAS)

10. Moscow

11. Russia

Abstract

The higher the charge density of PILs the higher their T_g and the lower their conductivity; the best conductivity (1.8 × 10⁻⁵ S cm⁻¹ at 25 °C): PILs with triazolium cations; the best cathodic stability (−0.4 V vs. Li⁺/Li at 70 °C): PILs with mixed type cations.

Funder

Fonds National de la Recherche Luxembourg

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ04143B

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