Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with UIV–E–UIV cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange

Abstract

Analysis of U^IV–E–U^IV (E = S, Se, Te) complexes reveals their behaviour is due to crystal field effects and not exchange coupling.