Exploring the localized to delocalized transition in non-symmetric bimetallic ruthenium polypyridines-Reference-Cited by-同舟云学术

Exploring the localized to delocalized transition in non-symmetric bimetallic ruthenium polypyridines

Published:2017 Issue:45 Volume:46 Page:15757-15768
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Oviedo Paola S.¹²³⁴⁵^ORCID,Pieslinger German E.¹²³⁴⁵^ORCID,Cadranel Alejandro¹²³⁴⁵^ORCID,Baraldo Luis M.¹²³⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires

2. Facultad de Ciencias Exactas y Naturales

3. Departamento de Química Inorgánica

4. Analítica y Química Física

5. Buenos Aires

Abstract

Modification of the ligand L in the mixed-valence cyanide-bridged complexes [Ru(tpy)(bpy)(μ-CN)Ru(bpy)₂(L)]^3+/4+ (L= Cl⁻ (1²⁺), NCS⁻ (2³⁺), 4-dimethylaminopyridine (3⁴⁺) or acetonitrile (4⁴⁺)) reduces the difference between the redox potentials of the ruthenium ions and leads to a transition from a localized to a delocalized configuration.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02422C

Reference90 articles.

1. Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells

2. Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications

3. Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells

4. Mixed valence: origins and developments

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