Comparing the electronic relaxation dynamics of aniline and d7-aniline following excitation at 272

Comparing the electronic relaxation dynamics of aniline and d7-aniline following excitation at 272–238 nm

Published:2015 Issue:25 Volume:17 Page:16270-16276
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kirkby Oliver M.¹²³⁴,Sala Matthieu⁵⁶⁷⁸,Balerdi Garikoitz⁹¹⁰¹¹¹²¹³,de Nalda Rebeca¹⁴¹⁵¹⁶¹³,Bañares Luis⁹¹⁰¹¹¹²¹³,Guérin Stéphane⁵⁶⁷⁸,Fielding Helen H.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University College London

3. London WC1H 0AJ

4. UK

5. Laboratoire Interdisciplinaire Carnot de Bourgogne UMR 6303 CNRS

6. Université Bourgogne Franche-Comté

7. F-21078 Dijon Cedex

8. France

9. Departamento de Química Física I (Unidad Asociada I + D + i al CSIC)

10. Facultad de Ciencias Químicas

11. Universidad Complutense de Madrid

12. 28040 Madrid

13. Spain

14. Instituto de Química Física Rocasolano

15. CSIC

16. 28006 Madrid

Abstract

Femtosecond studies of electronic relaxation in aniline reveal evidence for a 3-state conical intersection and show that tunnelling is unimportant.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01883H

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