Cu(OAc)2-promoted reaction of [60]fullerene with primary amines or diamines
Author:
Affiliation:
1. School of Petrochemical Engineering
2. Changzhou University
3. Changzhou 213164
4. China
5. Key Laboratory of Novel Thin Film Solar Cells
6. Institute of Plasma Physics
7. Chinese Academy of Sciences
8. Hefei 230031
Abstract
The Cu(OAc)2-mediated oxidative dehydrogenative addition of easily available primary amines to C60 allows the concise preparation of aziridinofullerenes. Moreover, the Cu(OAc)2-promoted reaction of C60 with diamines affords C60-fused cyclic 1,2-diaminated fullerenes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01048A
Reference64 articles.
1. Aziridination of C60 with Simple Amides and Catalytic Rearrangement of the Aziridinofullerenes to Azafulleroids
2. Aziridinofullerene: A Versatile Platform for Functionalized Fullerenes
3. PCy3-Catalyzed Ring Expansion of Aziridinofullerenes with CO2and Aryl Isocyanates: Evidence for a Two Consecutive Nucleophilic Substitution Pathway on the Fullerene Cage
4. BF3·Et2O-Catalyzed Formal [3 + 2] Reaction of Aziridinofullerenes with Carbonyl Compounds
5. BF3·Et2O- or DMAP-Catalyzed Double Nucleophilic Substitution Reaction of Aziridinofullerenes with Sulfamides or Amidines
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