A homochiral vanadium–salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation

Author:

Bhunia Asamanjoy12345,Dey Subarna6789,Moreno José María101112,Diaz Urbano101112,Concepcion Patricia101112,Van Hecke Kristof14513,Janiak Christoph6789,Van Der Voort Pascal12345ORCID

Affiliation:

1. Department of Inorganic and Physical Chemistry

2. Center for Ordered Materials

3. Organometallics and Catalysis

4. Ghent University

5. 9000 Ghent

6. Institut für Anorganische Chemie und Strukturchemie

7. Universität Düsseldorf

8. 40204 Düsseldorf

9. Germany

10. Instituto de Tecnología Quimica (UPV-CSIC)

11. 46022 Valencia

12. Spain

13. Belgium

Abstract

This chiral framework shows the highest H2 adsorption and CO2 capacity for currently known salen-based MOFs and shows an excellent performance as an asymmetric catalyst in solvent-free cyanosilylation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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