Ni(i)–Ni(iii) cycle in Buchwald–Hartwig amination of aryl bromide mediated by NHC-ligated Ni(i) complexes-Reference-Cited by-同舟云学术

Ni(i)–Ni(iii) cycle in Buchwald–Hartwig amination of aryl bromide mediated by NHC-ligated Ni(i) complexes

Published:2019 Issue:8 Volume:9 Page:1784-1793
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Inatomi Takahiro¹²³⁴,Fukahori Yukino¹²³⁴,Yamada Yuji¹²³⁴,Ishikawa Ryuta¹²³⁴^ORCID,Kanegawa Shinji⁵⁶⁷⁴,Koga Yuji¹²³⁴,Matsubara Kouki¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Fukuoka University

3. Fukuoka 814-0180

4. Japan

5. Institute for Advanced Materials Chemistry and Engineering

6. Kyushu University

7. Fukuoka 819-0395

Abstract

NHC-ligated Ni(i) intermediates in Buchwald–Hartwig amination of aryl halides were isolated and determined. The presence of a Ni(iii) intermediate was also indicated at low temperature.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CY/C8CY02427H

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