Barium-promoted hydrothermal stability of monolithic Cu/BEA catalyst for NH3-SCR

Author:

Lin Qingjin12345,Liu Jingying12345,Liu Shuang12345,Xu Shuhao12345,Lin Chenlu12345,Feng Xi6758,Wang Yun6758,Xu Haidi9410811,Chen Yaoqiang12345ORCID

Affiliation:

1. Key Laboratory of Green Chemistry & Technology

2. Ministry of Education

3. College of Chemistry

4. Sichuan University

5. Chengdu

6. Sinocat Environmental Technology Co.

7. Ltd

8. China

9. Institute of New Energy and Low-Carbon Technology

10. Chengdu 610064

11. National Engineering Laboratory for Mobile Source Emission Control Technology

Abstract

The addition of Ba on the improvement of hydrothermal stability over Cu/BEA: (i) stabilize the dispersion of Cu species and suppress the formation of CuO clusters; (ii) the higher redox property. These two factors decide the higher hydrothermal stability over CuBa/BEA-HT rather than Cu/BEA-HT.

Funder

National Natural Science Foundation of China

Sichuan Province Science and Technology Support Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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