Lithium–bromine exchange reaction on C60: first theoretical proposal of a stable singlet fullerene carbene without the heteroatom-Reference-Cited by-同舟云学术

Lithium–bromine exchange reaction on C60: first theoretical proposal of a stable singlet fullerene carbene without the heteroatom

Published:2021 Issue:7 Volume:8 Page:1551-1562
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Li Mengyang¹²³⁴⁵,Zhao Yaoxiao¹²³⁴⁵,Yuan Kun⁶⁷⁸⁵,Han Yanbo¹²³⁴⁵,Zhang Jie¹²³⁴⁵,Wu Yong¹²³⁴⁵^ORCID,Ehara Masahiro⁹¹⁰¹¹^ORCID,Nagase Shigeru¹²¹³¹⁴¹¹,Zhao Xiang¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Molecular Science & Applied Chemistry

2. School of Chemistry

3. Xi'an Jiaotong University

4. Xi'an

5. China

6. College of Chemical Engineering and Technology

7. Tianshui Normal University

8. Tianshui

9. Institute for Molecular Science

10. Okazaki

11. Japan

12. Fukui Institute for Fundamental Chemistry

13. Kyoto University

14. Kyoto 606-8103

Abstract

A stable singlet fullerene carbene without heteroatom is firstly proposed, and two indexes are firstly suggested to estimate the occurrence of carbene insertion or addition. The interaction between LiBr and carbon atom in LiBr-compounds is explored.

Funder

National Natural Science Foundation of China

Ministry of Education, Culture, Sports, Science and Technology

Natural Science Foundation of Gansu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01589J

Reference70 articles.

1. Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes