Identification of reaction intermediates in the decomposition of formic acid on Pd-Reference-Cited by-同舟云学术

Identification of reaction intermediates in the decomposition of formic acid on Pd

Published:2024 Issue: Volume:251 Page:412-434
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Fingerhut Jan¹^ORCID,Lecroart Loïc²,Schwarzer Michael¹,Hörandl Stefan¹,Borodin Dmitriy¹²^ORCID,Kandratsenka Alexander²,Kitsopoulos Theofanis N.²³^ORCID,Auerbach Daniel J.²^ORCID,Wodtke Alec M.¹²⁴^ORCID

Affiliation:

1. Institute for Physical Chemistry, Georg-August University of Goettingen, 37077 Goettingen, Germany

2. Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, 37077 Goettingen, Germany

3. School of Mathematics and Natural Sciences, University of Southern Mississippi, Hattiesburg, MS 39406, USA

4. International Center for Advanced Studies of Energy Conversion, Georg-August University of Goettingen, 37077 Goettingen, Germany

Abstract

We report an approach to identify intermediates for the formic acid decomposition reaction on Pd(111) and Pd(332) based on accurate measurements of isotopologue specific thermal reaction rates.

Funder

Deutsche Forschungsgemeinschaft

HORIZON EUROPE European Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/FD/D3FD00174A

Reference45 articles.

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5. Mechanistic Study of Electrocatalytic Oxidation of Formic Acid at Platinum in Acidic Solution by Time-Resolved Surface-Enhanced Infrared Absorption Spectroscopy