Elucidating metal hydride reactivity using late transition metal boryl and borane hydrides: 2c–2e terminal hydride, 3c–2e bridging hydride, and 3c–4e bridging hydride
Author:
Affiliation:
1. School of Materials Science & Engineering
2. PCFM Lab
3. School of Chemistry
4. Sun Yat-sen University
5. Guangzhou 510275
6. College of Chemistry and Molecular Engineering
7. Zhengzhou University
8. Zhengzhou 450001
9. People's Republic of China
Abstract
A general trend for the hydrogenation reactivity of metal hydride(s): 3c–4e bridging hydride > 2c–2e terminal hydride > 3c–2e bridging hydride.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Guangdong Province
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00766G
Reference40 articles.
1. Hydride complexes of the transition metals
2. Nickel Hydride Complexes
3. Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts
4. Asymmetric transfer hydrogenation: chiral ligands and applications
5. Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage
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