Elucidating metal hydride reactivity using late transition metal boryl and borane hydrides: 2c–2e terminal hydride, 3c–2e bridging hydride, and 3c–4e bridging hydride-Reference-Cited by-同舟云学术

Elucidating metal hydride reactivity using late transition metal boryl and borane hydrides: 2c–2e terminal hydride, 3c–2e bridging hydride, and 3c–4e bridging hydride

Published:2018 Issue:13 Volume:8 Page:3395-3405
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Li Yinwu¹²³⁴⁵,Liu Jiahao¹²³⁴⁵,Hou Cheng¹²³⁴⁵,Shao Youxiang¹²³⁴⁵,Qu Ling-Bo⁶⁷⁸⁹,Zhao Cunyuan¹²³⁴⁵,Ke Zhuofeng¹²³⁴⁵^ORCID

Affiliation:

1. School of Materials Science & Engineering

2. PCFM Lab

3. School of Chemistry

4. Sun Yat-sen University

5. Guangzhou 510275

6. College of Chemistry and Molecular Engineering

7. Zhengzhou University

8. Zhengzhou 450001

9. People's Republic of China

Abstract

A general trend for the hydrogenation reactivity of metal hydride(s): 3c–4e bridging hydride > 2c–2e terminal hydride > 3c–2e bridging hydride.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00766G

Reference40 articles.

1. Hydride complexes of the transition metals

2. Nickel Hydride Complexes

3. Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts

4. Asymmetric transfer hydrogenation: chiral ligands and applications

5. Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage

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