Comparative study of donor atom effects on the thermodynamic and electron-transfer kinetic properties of copper(ii/i) complexes with sexadentate macrocyclic ligands. [CuII/I([18]aneS4N2)] and [CuII/I([18]aneS4O2)]-Reference-Cited by-同舟云学术

Comparative study of donor atom effects on the thermodynamic and electron-transfer kinetic properties of copper(ii/i) complexes with sexadentate macrocyclic ligands. [CuII/I([18]aneS4N2)] and [CuII/I([18]aneS4O2)]

Published:2007 Issue:4 Volume: Page:449-458
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Chaka Gezahegn,Kandegedara Ashoka,Heeg Mary Jane,Rorabacher D. B.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2007/DT/B612252C

Reference61 articles.

1. Structure-reactivity relationships in copper(II)/copper(I) electron-transfer kinetics: evaluation of self-exchange rate constants for copper polythia ether complexes

2. Water-soluble crown thia ethers: investigation of pH, anion, and steric effects on the equilibria and kinetics of aquocopper(II) ion reacting with alcoholic derivatives of a macrocyclic tetrathia ether ligand

3. Evidence for a square scheme involving conformational intermediates in electron-transfer reactions of copper(II)/(I) systems

4. Direct determination of the self-exchange electron-transfer rate constant for a copper(II/I) macrocyclic pentathiaether complex

5. Gated electron-transfer behavior in copper(II/I) systems. Comparison of the kinetics for homogeneous cross reactions, NMR self-exchange relaxation, and electrochemical data for a copper macrocyclic tetrathioether complex in aqueous solution

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