On the conversion of CO2 to value added products over composite PdZn and H-ZSM-5 catalysts: excess Zn over Pd, a compromise or a penalty?-Reference-Cited by-同舟云学术

On the conversion of CO2 to value added products over composite PdZn and H-ZSM-5 catalysts: excess Zn over Pd, a compromise or a penalty?

Published:2020 Issue:13 Volume:10 Page:4373-4385
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Ahoba-Sam Christian¹²³⁴⁵^ORCID,Borfecchia Elisa²⁶⁷⁸⁹^ORCID,Lazzarini Andrea¹²³⁴⁵^ORCID,Bugaev Aram¹⁰¹¹¹²¹³¹⁴^ORCID,Isah Abdulrahman Adamu¹⁵¹⁶¹⁷¹⁸¹⁹,Taoufik Mostafa¹⁵¹⁶¹⁷¹⁸¹⁹,Bordiga Silvia¹²³⁴⁵^ORCID,Olsbye Unni¹²³⁴⁵^ORCID

Affiliation:

1. SMN Centre for Materials Science and Nanotechnology

2. Department of Chemistry

3. University of Oslo

4. N-0315 Oslo

5. Norway

6. NIS Center and INSTM Reference Center

7. University of Turin

8. Turin

9. Italy

10. The Smart Materials Research Institute

11. Southern Federal University

12. Rostov-on-Don

13. Russia

14. Southern Scientific Centre

15. Université Lyon 1

16. Institut de Chimie Lyon

17. CPE Lyon CNRS

18. UMR 5265 C2P2

19. LCOMS

Abstract

Zn was found to possess a dual role in composite PdZn–H-ZSM-5 catalysts for CO₂ hydrogenation reactions: it promotes methanol formation when alloyed with Pd, but inhibits hydrocarbon formation by ion exchange with Brønsted acid sites in H-ZSM-5.

Funder

Norges Forskningsråd

Russian Science Foundation

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY00440E

Reference65 articles.

1. A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons

2. Global warming and carbon dioxide through sciences

3. World Energy agency , Overview and key findings

4. Thermodynamics in Methanol Synthesis

5. J. B. Hansen and P. E.Højlund Nielsen , in Handbook of Heterogeneous Catalysis , ed. G. Ertl , H. Knözinger , F. Schüth , J. Weitkamp , H. G. Karge and H. Pfeifer , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2008 , pp. 2920–2949

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Zn Redistribution and Volatility in ZnZrO_x Catalysts for CO₂ Hydrogenation;Chemistry of Materials;2023-12-11

2. CO2 utilization in syngas conversion to dimethyl ether and aromatics: Roles and challenges of zeolites-based catalysts;Journal of Energy Chemistry;2023-04

3. PdZn/ZrO2+SAPO-34 bifunctional catalyst for CO2 conversion: Further insights by spectroscopic characterization;Applied Catalysis A: General;2023-04

4. Evolution of surface and bulk structure of supported palladium nanoparticles by in situ X-ray absorption and infrared spectroscopies: Effect of temperature, CO and CH4 gas;Applied Surface Science;2023-03

5. From Lab to Technical CO₂ Hydrogenation Catalysts: Understanding PdZn Decomposition;ACS Applied Materials & Interfaces;2023-01-23