Selective defunctionalization of citric acid to tricarballylic acid as a precursor for the production of high-value plasticizers

Author:

Stuyck Wouter12345ORCID,Verduyckt Jasper12345ORCID,Krajnc Andraž678,Mali Gregor678ORCID,De Vos Dirk E.12345ORCID

Affiliation:

1. Centre for Membrane Separations

2. Adsorption

3. Catalysis and Spectroscopy for Sustainable Solutions (cMACS)

4. KU Leuven

5. 3001 Leuven

6. National Institute of Chemistry

7. 1001 Ljubljana

8. Slovenia

Abstract

In presence of a solid acid H-Beta zeolite and Pd/C catalyst, citric acid was converted to tricarballylic acid via a one-pot sequential dehydration-hydrogenation process with a yield up to 85% and a selectivity exceeding 90%.

Funder

Fonds Wetenschappelijk Onderzoek

KU Leuven

Javna Agencija za Raziskovalno Dejavnost RS

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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5. P. Walters , D. F.Cadogan and C. J.Howick , Plasticizers in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag , Germany , 2020 , pp. 1–27

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