Fluorinated boron subphthalocyanines: Lewis acid based templating chemistry facilitates random halide exchange, and fluoride versus chloride affects the basic photophysical properties and the solid-state arrangement
Author:
Affiliation:
1. Department of Chemical Engineering and Applied Chemistry
2. University of Toronto
3. Toronto
4. Canada
5. Schulich Faculty of Chemistry
6. Israel Institute of Technology (Technion)
7. Haifa 3200008
8. Israel
9. Department of Chemistry
Abstract
A sub-group of the phthalocyanine family, the boron subphthalocyanines (BsubPcs), have robust chemistry and can be readily modified at the axial and peripheral positions to tune their physical properties.
Funder
Natural Sciences and Engineering Research Council of Canada
University of Toronto
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ04093E
Reference63 articles.
1. Subphthalocyanines, Subporphyrazines, and Subporphyrins: Singular Nonplanar Aromatic Systems
2. Boron Subphthalocyanines as Organic Electronic Materials
3. Experimentally Validated Model for the Prediction of the HOMO and LUMO Energy Levels of Boronsubphthalocyanines
4. Outdoor Performance and Stability of Boron Subphthalocyanines Applied as Electron Acceptors in Fullerene-Free Organic Photovoltaics
5. 8.4% efficient fullerene-free organic solar cells exploiting long-range exciton energy transfer
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