Competing synclinic and anticlinic interactions in smectic phases of bent-core mesogens

Author:

Svoboda Jiří1ORCID,Kozmík Václav1,Bajzíková Kvetoslava1,Kohout Michal1ORCID,Novotná Vladimíra2ORCID,Podoliak Natalia2ORCID,Pociecha Damian3ORCID,Gorecka Ewa3ORCID

Affiliation:

1. Department of Organic Chemistry, University of Chemistry and Technology, CZ-166 28 Prague 6, Czech Republic

2. Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, CZ-182 21 Prague 8, Czech Republic

3. Faculty of Chemistry, University of Warsaw, ul. Zwirki i Wigury 101, 02-089 Warsaw, Poland

Abstract

Presented molecules combine two features, the bent-core rigidity with the dimeric character, and reveal variety of specific phases. Longer homologues exhibit tilted smectic phases, short homologues manifest a propensity for helical structures.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

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