Enantioselective iodolactonization to prepare ε-lactone rings using hypervalent iodine-Reference-Cited by-同舟云学术

Enantioselective iodolactonization to prepare ε-lactone rings using hypervalent iodine

Published:2022 Issue:24 Volume:13 Page:7318-7324
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Payne Jenna L.¹^ORCID,Deng Zihang¹^ORCID,Flach Andrew L.¹,Johnston Jeffrey N.¹^ORCID

Affiliation:

1. Department of Chemistry, Vanderbilt Institute of Chemical Biology, Vanderbilt University, Nashville, Tennessee 37235-1822, USA

Abstract

We describe the first highly enantioselective 7-exo-trig iodolactonizations of conformationally unbiased ε-unsaturated carboxylic acids, effected by an unusual combination of a bifunctional BAM catalyst, I2, and I(iii) reagent (PhI(OAc)2:PIDA).

Funder

Division of Chemistry

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01587K

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