Dynamics of isobutane is a sensitive probe for framework breathing in MIL-53 (Al) MOF-Reference-Cited by-同舟云学术

Dynamics of isobutane is a sensitive probe for framework breathing in MIL-53 (Al) MOF

Published:2020 Issue:33 Volume:22 Page:18695-18702
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Khudozhitkov Alexander E.¹²³⁴⁵,Arzumanov Sergei S.¹²³⁴⁵^ORCID,Gabrienko Anton A.¹²³⁴⁵^ORCID,Kolokolov Daniil I.¹²³⁴⁵^ORCID,Stepanov Alexander G.¹²³⁴⁵^ORCID

Affiliation:

1. Boreskov Institute of Catalysis

2. Siberian Branch of Russian Academy of Sciences

3. Novosibirsk 630090

4. Russia

5. Novosibirsk State University

Abstract

²H solid-state NMR shows that the dynamics of adsorbed isobutane is very sensitive to MIL-53 framework breathing detected by ²⁷Al MAS NMR.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP03271A

Reference50 articles.

1. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy

2. A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration

3. Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47

4. How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53

5. Synthesis, characterization, and CO2 adsorption of three metal-organic frameworks (MOFs): MIL-53, MIL-96, and amino-MIL-53

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