Stabilization of ultra-small [Ag2]2+ and [Agm]n+ nano-clusters through negatively charged tetrahedrons in oxyfluoride glass networks: To largely enhance the luminescence quantum yields

Author:

Ma Ronghua12345,Zhao Junjie12345,Chen Xiaotong12345,Qiao Xvsheng12345ORCID,Fan Xianping12345,Du Jincheng6789,Zhang Xianghua1011121314

Affiliation:

1. State Key Laboratory of Silicon Materials

2. School of Materials Science and Engineering

3. Zhejiang University

4. Hangzhou 310027

5. China

6. Department of Materials Science and Engineering

7. University of North Texas

8. Denton

9. USA

10. Laboratory of Glasses and Ceramics

11. Institute of Chemical Science UMR CNRS 6226

12. University of Rennes 1

13. 35042 Rennes

14. France

Abstract

Sub-nanometer [Ag2]2+ and [Agm]n+ were highly stabilized in inorganic glass to achieve heavy doping and high luminescence QYs.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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