Reaction of sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl) benzenesulfonate with ethylenediamine on Cu(ii) and Ni(ii) centres: efficient Cu(ii) homogeneous catalysts for cyanosilylation of aldehydes-Reference-Cited by-同舟云学术

Reaction of sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl) benzenesulfonate with ethylenediamine on Cu(ii) and Ni(ii) centres: efficient Cu(ii) homogeneous catalysts for cyanosilylation of aldehydes

Published:2016 Issue:59 Volume:6 Page:54263-54269
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Mahmoud Abdallah G.¹²³⁴⁵,Mahmudov Kamran T.¹²³⁴⁵,Guedes da Silva M. Fátima C.¹²³⁴⁵,Pombeiro Armando J. L.¹²³⁴⁵

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 1049-001 Lisboa

5. Portugal

Abstract

Reaction of sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl)benzenesulfonate with ethylenediamine on Cu(ii) and Ni(ii) centres lead to variety of metal complexes which effectively catalyse the cyanosilylation of aldehydes with trimethylsilyl cyanide.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA12274D

Reference30 articles.

1. Cooperative Metal–Ligand Assisted E/Z Isomerization and Cyano Activation at CuII and CoII Complexes of Arylhydrazones of Active Methylene Nitriles

2. Lanthanide derivatives comprising arylhydrazones of β-diketones: cooperative E/Z isomerization and catalytic activity in nitroaldol reaction

3. Hydrazone-based switches, metallo-assemblies and sensors

4. Coordination chemistry of arylhydrazones of methylene active compounds

5. Solid-State N–H···O/O–H···N Tautomerism in Resonance-Assisted 1-(Arylazo)-2-Naphthols and Its Through-Space π* ← π Perturbation in TCNQ Cocrystals. A Variable-Temperature X-ray Crystal Study

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