Diaqua-β-octaferrocenyltetraphenylporphyrin: a multiredox-active and air-stable 16π non-aromatic species-Reference-Cited by-同舟云学术

Diaqua-β-octaferrocenyltetraphenylporphyrin: a multiredox-active and air-stable 16π non-aromatic species

Published:2019 Issue:5 Volume:48 Page:1578-1585
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Al-Shewiki Rasha K.¹²³⁴,Korb Marcus¹²³⁴^ORCID,Hildebrandt Alexander¹²³⁴^ORCID,Zahn Stefan⁵⁶⁴^ORCID,Naumov Sergej⁵⁶⁴,Buschbeck Roy¹²³⁴,Rüffer Tobias¹²³⁴^ORCID,Lang Heinrich¹²³⁴^ORCID

Affiliation:

1. Chemnitz University of Technology

2. Inorganic Chemistry

3. 09111 Chemnitz

4. Germany

5. Leibniz-Institut für Oberflächenmodifizierung e.V.

6. 04318 Leipzig

Abstract

Herein the synthesis and properties of the first β-octaferrocenyltetraphenylporphyrin, {TPPFc₈(H₂O)₂}, in its extraordinary stable and non-aromatic 16π form are reported, showing seven separate reversible redox events.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04135K

Reference118 articles.

1. Ethynylferrocene Compounds of 1,3,5-Tribromobenzene

2. Octamethylferrocenylethynyl units as peripheral groups in rigid, π-conjugated molecular architectures

3. A Simple and Efficient Synthesis of Di-, Tri-, and Tetraferrocenylarenes