Benzo-thia-fused [n]thienoacenequinodimethanes with small to moderate diradical characters: the role of pro-aromaticity versus anti-aromaticity-Reference-Cited by-同舟云学术

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Benzo-thia-fused [n]thienoacenequinodimethanes with small to moderate diradical characters: the role of pro-aromaticity versus anti-aromaticity

Published:2016 Issue:5 Volume:7 Page:3036-3046
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shi Xueliang¹²³,Quintero Estefanía⁴⁵⁶⁷,Lee Sangsu¹⁸⁹¹⁰,Jing Linzhi¹²³,Herng Tun Seng¹¹²³,Zheng Bin¹²¹³¹⁴¹⁵,Huang Kuo-Wei¹²¹³¹⁴¹⁵,López Navarrete Juan T.⁴⁵⁶⁷,Ding Jun¹¹²³,Kim Dongho¹⁸⁹¹⁰,Casado Juan⁴⁵⁶⁷,Chi Chunyan¹²³

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. Singapore

4. Department of Physical Chemistry

5. University of Malaga

6. 229071 Malaga

7. Spain

8. Yonsei University

9. Seoul 120-749

10. Korea

11. Department of Materials Science & Engineering

12. Division of Physical Science and Engineering and KAUST Catalysis Center

13. King Abdullah University of Science and Technology (KAUST)

14. Thuwal 23955-6900

15. Kingdom of Saudi Arabia

Abstract

Pro-aromatic Thn-TIPS exhibits distinctly different physical properties from anti-aromatic Sn-TIPS.

Funder

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04706D

Reference80 articles.

1. Low band gap polycyclic hydrocarbons: from closed-shell near infrared dyes and semiconductors to open-shell radicals

2. Theoretical consideration of singlet open-shell character of polyperiacenes using Clar's aromatic sextet valence bond model and quantum chemical calculations

3. Quinoidal oligothiophenes: new properties behind an unconventional electronic structure

4. Benzenoid Polycyclic Hydrocarbons with an Open-Shell Biradical Ground State

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