A mechanistic investigation of the photoinduced, copper-mediated cross-coupling of an aryl thiol with an aryl halide-Reference-Cited by-同舟云学术

A mechanistic investigation of the photoinduced, copper-mediated cross-coupling of an aryl thiol with an aryl halide

Published:2016 Issue:7 Volume:7 Page:4091-4100
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Johnson Miles W.¹²³⁴,Hannoun Kareem I.¹²³⁴,Tan Yichen¹²³⁴,Fu Gregory C.¹²³⁴,Peters Jonas C.¹²³⁴

Affiliation:

1. Division of Chemistry and Chemical Engineering

2. California Institute of Technology

3. Pasadena, CA

4. USA

Abstract

A mechanistic study establishes the viability of a copper-mediated pathway for photoinduced C–S cross-coupling involving single electron transfer and in-cage radical recombination.

Funder

National Institute for Health Research

Gordon and Betty Moore Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04709A

Reference45 articles.

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3. G. Evano and N.Blanchard, Copper-Mediated Cross-Coupling Reactions, John Wiley & Sons, Hoboken, NJ, 2014

4. Photoinduced Ullmann C–N Coupling: Demonstrating the Viability of a Radical Pathway

5. A New Family of Nucleophiles for Photoinduced, Copper-Catalyzed Cross-Couplings via Single-Electron Transfer: Reactions of Thiols with Aryl Halides Under Mild Conditions (O °C)

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