Dimerization and ring-opening in bis(diisopropylamino)cyclopropenylidene (BAC) mediated by [U(NR2)3(CCPh)] (R = SiMe3)-Reference-Cited by-同舟云学术

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Dimerization and ring-opening in bis(diisopropylamino)cyclopropenylidene (BAC) mediated by [U(NR₂)₃(CCPh)] (R = SiMe₃)

Published:2023 Issue:39 Volume:52 Page:13868-13871
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nguyen Thien H.¹^ORCID,Pauly Christophe¹,Kent Greggory T.¹,Wu Guang¹,Hayton Trevor W.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106, USA

Abstract

Addition of bis(diisopropylamino)cyclopropenylidene (BAC) to [U(NR2)3(CCPh)] (R = SiMe3) results in dimerization and protonation of two BAC molecules, followed by ring-opening and C–H activation to generate a azetidin-2-ylidenemethyl ring.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02741D

Reference62 articles.

1. Synthesis and characterization of the tetra-aminotriafulvalene dication

2. Isolation of Cyclopropenylidene–Lithium Adducts: The Weiss–Yoshida Reagent

3. Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory

4. SE Reactions on the C3+-Ring:σ-Attack

5. SE Reactions on the C3+-Ring:π-Attack

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