An electrochemically controlled supramolecular zip tie based on host–guest chemistry of CB[8]

Author:

Neira Iago12345ORCID,Domarco Olaya12345,Barriada Jose L.12345ORCID,Franchi Paola678,Lucarini Marco678ORCID,García Marcos D.12345ORCID,Peinador Carlos12345ORCID

Affiliation:

1. Departamento de Química and Centro de Investigaciones

2. Científicas Avanzadas (CICA)

3. Universidade da Coruña

4. Facultad de Ciencias

5. E-15071 A Coruña

6. Department of Chemistry “G. Ciamician” – Alma Mater Studiorum-University of Bologna

7. Bologna

8. Italy

Abstract

A stimuli-responsive supramolecular assembly based on a bipyridinium thread and CB[8] behaves like a zip tie relaxing the chain as a consequence of the insertion of both radical cation moieties within the CB[8] macrocycle.

Funder

Ministerio de Economía y Competitividad

Xunta de Galicia

Ministerio de Educación, Cultura y Deporte

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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