Unravelling the CO2 capture and conversion mechanism of a NiRu–Na2O switchable dual-function material in various CO2 utilisation reactions

Author:

Merkouri Loukia-Pantzechroula1,Martín-Espejo Juan Luis2,Bobadilla Luis F.2,Odriozola José Antonio2ORCID,Penkova Anna2,Ramirez Reina Tomas2,Duyar Melis S.1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, University of Surrey, Guildford, GU2 7XH, UK

2. Department of Inorganic Chemistry and Materials Sciences Institute, University of Seville-CSIC, 41092, Seville, Spain

Abstract

The mechanism of a NiRuNa/CeAl dual function material in successive cycles of CO2 capture and conversion was investigated. Carbonyls and carbonates were formed during CO2 capture, and a spillover mechanism occurred to form the desired products.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference48 articles.

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3. United Nations , Climate change: No ‘credible pathway’ to 1.5C limit , UNEP warns , accessed 3 March 2023 , https://news.un.org/en/story/2022/10/1129912

4. IEA , An updated roadmap to Net Zero Emissions by 2050 , accessed 9 December 2022 , https://www.iea.org/reports/world-energy-outlook-2022/an-updated-roadmap-to-net-zero-emissions-by-2050

5. IEA , CCUS in the transition to net-zero emissions , accessed 3 March 2023 , https://www.iea.org/reports/ccus-in-clean-energy-transitions/ccus-in-the-transition-to-net-zero-emissions

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