Electronegativity and redox reactions
Author:
Affiliation:
1. Laboratory of Computational and Theoretical Chemistry
2. Faculty of Chemistry
3. University of Havana
4. Havana
5. Cuba
6. Department of Chemistry & Chemical Biology
7. McMaster University
8. Hamilton
9. Canada
Abstract
Using the maximum hardness principle, we show that the oxidation potential of a molecule increases as its electronegativity increases and also increases as its electronegativity in its oxidized state increases.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03213C
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1. Accurate Oxidation Potentials of Benzene and Biphenyl Derivatives via Electron-Transfer Equilibria and Transient Kinetics
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3. Reaction to Why Do We Teach Equilibrium Calculations?
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5. Single-Ion Solvation Free Energies and the Normal Hydrogen Electrode Potential in Methanol, Acetonitrile, and Dimethyl Sulfoxide
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