Light-promoted copper-catalyzed cage C-arylation of o-carboranes: facile synthesis of 1-aryl-o-carboranes and o-carborane-fused cyclics

Author:

Ni Hangcheng1,Lu Zhenpin1ORCID,Xie Zuowei1ORCID

Affiliation:

1. Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, China

Abstract

Light-promoted, copper catalyzed cage C–H arylation of o-carboranes with aryl halides has been achieved, leading to the facile synthesis of a variety of 1-aryl-o-carboranes and o-carborane-fused cyclics.

Funder

Research Grants Council, University Grants Committee

Chinese University of Hong Kong

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference62 articles.

1. R. N.Grimes , Carboranes , Elsevier , Oxford , 2nd edn, 2011

2. N. S.Hosmane , Boron Science: New Technologies and Applications , Taylor & Francis Books/CRC , Boca Raton, FL , 2011

3. Recent advances in transition metal-mediated functionalization of o-carboranes

4. Methods to produce B–C, B–P, B–N and B–S bonds in boron clusters

5. Carbaboranes as Pharmacophores: Properties, Synthesis, and Application Strategies

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