Synthesis of diblock copolymer spheres, worms and vesicles via RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate-Reference-Cited by-同舟云学术

Synthesis of diblock copolymer spheres, worms and vesicles via RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate

Published:2021 Issue:25 Volume:12 Page:3629-3639
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Hunter Saul J.¹²³⁴⁵^ORCID,Lovett Joseph R.¹²³⁴⁵,Mykhaylyk Oleksandr O.¹²³⁴⁵^ORCID,Jones Elizabeth R.⁶⁷⁸,Armes Steven P.¹²³⁴⁵^ORCID

Affiliation:

1. Dainton Building

2. Department of Chemistry

3. The University of Sheffield

4. Sheffield

5. UK

6. DSM Applied Science Centre

7. 6160 BB Geleen

8. The Netherlands

Abstract

RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate using a poly(glycerol monomethacrylate) precursor leads to diblock copolymer spheres, worms or vesicles. A pseudo-phase diagram is constructed and the vesicles are briefly evaluated as a Pickering emulsifier.

Funder

Engineering and Physical Sciences Research Council

DSM Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00517K

Reference94 articles.

1. Ab Initio Emulsion Atom‐Transfer Radical Polymerization

2. Controlled/Living Radical Polymerization in Dispersed Systems: An Update