Design of FeIII–LnIII binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis

Author:

Topor Alexandru1ORCID,Liu Dan2ORCID,Maxim Catalin1,Novitchi Ghenadie3,Train Cyrille3ORCID,AlOthman Zeid A.4ORCID,Al-Kahtani Abdullah A. S.4,Ungur Liviu5ORCID,Ho Le Tuan Anh5ORCID,Chibotaru Liviu F.46,Andruh Marius17ORCID

Affiliation:

1. University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, 020464-Bucharest, Romania

2. Institute of Flexible Electronics, Northwestern Polytechnical University, 127 West Youyi Road, Xi’an, 710072, Shaanxi, China

3. CNRS, Univ. Grenoble Alpes, LNCMI, F-38000 Grenoble, France

4. Chemistry Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia

5. Department of Chemistry, National University of Singapore, Block S8 Level 3, 3 Science Drive 3, Singapore 117543

6. Theory of Nanomaterials Group, Department of Chemistry KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

7. C. D. Nenitzescu Institute of Organic Chemistry of the Romanian Academy, Splaiul Independentei 202B, Bucharest, Romania

Abstract

Rare examples of phenoxido-bridged FeIII–LnIII binuclear complexes are synthesized, and their dynamic and static magnetic properties are rationalized by ab initio calculations.

Funder

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Natural Science Foundation of Shaanxi Province

National University of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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