Salt metathesis as an alternative approach to access aluminium(i) and gallium(i) β-diketiminates-Reference-Cited by-同舟云学术

Salt metathesis as an alternative approach to access aluminium(i) and gallium(i) β-diketiminates

Published:2020 Issue:19 Volume:49 Page:6377-6383
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kysliak Oleksandr¹²³⁴,Görls Helmar¹²³⁴,Kretschmer Robert¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Inorganic and Analytical Chemistry (IAAC)

2. Friedrich Schiller University Jena

3. 07743 Jena

4. Germany

5. Jena Center for Soft Matter (JCSM)

Abstract

Aluminium(i) and gallium(i) β-diketiminates are accessed by a new route that provides better overall yields. In the case of aluminium it is also much faster, but some molecules turn into a dead end and merge into a dinuclear aluminium(iii) hydride.

Funder

Deutsche Forschungsgemeinschaft

Friedrich-Schiller-Universität Jena

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01342K

Reference80 articles.

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3. Four-Membered Group 13 Metal(I) N-Heterocyclic Carbene Analogues: Synthesis, Characterization, and Theoretical Studies

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5. Heavier Group 13 Metal(I) Heterocycles Stabilized by Sterically Demanding Diiminophosphinates: A Structurally Characterized Monomer-Dimer Pair For Gallium

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