Insight into non-covalent interactions in a [Cu(N3)4]2− bridged hetero-pentanuclear copper(<scp>ii</scp>)/sodium complex with special emphasis on the strong CH⋯π[Cu(N3)4] interactions-Reference-Cited by-同舟云学术

Insight into non-covalent interactions in a [Cu(N₃)₄]²⁻ bridged hetero-pentanuclear copper(ii)/sodium complex with special emphasis on the strong CH⋯π[Cu(N₃)₄] interactions

Published:2022 Issue:23 Volume:46 Page:11286-11295
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Bhaumik Prasanta Kumar¹^ORCID,Gomila Rosa M.²,Frontera Antonio²^ORCID,Benmansour Samia³^ORCID,Gómez-García Carlos J.³^ORCID,Chattopadhyay Shouvik⁴^ORCID

Affiliation:

1. Department of Chemistry, Bangabasi College, Kolkata, 700009, India

2. Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km7.5, 07122, Palma, Baleares, Spain

3. Departamento de Química Inorgánica, Universidad de Valencia, Dr Moliner 50, 46100, Burjasot, Valencia, Spain

4. Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata, 700032, India

Abstract

A hooked cross-shaped anion, [Cu(N3)4]2−, in a synthesized hetero-metallic pentanuclear copper(ii)–sodium complex provides a π-basic surface adequate for establishing a strong CH⋯[Cu(N3)4]2− interaction.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ00614F

Reference80 articles.

1. Komplexverbindungen des Kupfer(II)-azids. IV. Anlagerungsverbindungen [Cuprate]

2. Crystal Structure and Spectroscopic and Magnetic Properties of the Manganese(II) and Copper(II) Azido−Tetramethylammonium Systems

3. Synthese und Kristallstruktur von (Ph3PNPPh3)2[Cu(N3)4]

4. A copper(II) azide compound of pyrazinic acid containing a new dinuclear complex anion [Cu2(N3)6]2−. Synthesis, spectral and study of KCu2(pyrazinato) (N3)4

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