A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone-Reference-Cited by-同舟云学术

A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

Published:2019 Issue:48 Volume:48 Page:17704-17708
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Knoll Daniel M.¹²³⁴^ORCID,Zippel Christoph¹²³⁴^ORCID,Hassan Zahid¹²³⁴^ORCID,Nieger Martin⁵⁶⁷^ORCID,Weis Patrick⁸²³⁴^ORCID,Kappes Manfred M.⁹¹⁰¹¹⁴⁸^ORCID,Bräse Stefan¹²³⁴¹²^ORCID

Affiliation:

1. Institute of Organic Chemistry

2. Karlsruhe Institute of Technology (KIT)

3. 76131 Karlsruhe

4. Germany

5. Department of Chemistry

6. University of Helsinki

7. Finland

8. Institute of Physical Chemistry

9. Institute of Nanotechnology

10. Karlsruhe Institute of Technology

11. 76344 Eggenstein-Leopoldshafen

12. Institute of Toxicology and Genetics

Abstract

A highly stable and distance-defined [2.2]paracyclophane-based Au/Ru heterobimetallic complex shows promising catalytic properties in a visible-light mediated arylative Meyer–Schuster rearrangement.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT04366G

Reference38 articles.

1. Pronounced Ligand Effects and the Role of Formal Oxidation States in the Nickel-Mediated Thermal Activation of Methane

2. C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

3. Wide Bite Angle Diphosphines: Xantphos Ligands in Transition Metal Complexes and Catalysis